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Consider a generic redox reaction?
Consider a generic redox reaction X(s) + Y^+(aq) <----> X^+(aq) + Y(s) then suppose that the coefficients in the redox reaction are doubled. How will the following quantities be affected for a voltaic cell under nonstandard conditions? 1.Doubled 2. Halved 3. Squared 4. No Change The options are InQ, E^o, E, n, Q

Respuesta :

taskmasters
The Nernst equation allows us to predict the cell potential for voltaic cells under conditions other than the standard conditions of 1M, 1 atm, 25°C. The effects of different temperatures and concentrations may be tracked in terms of the Gibbs energy change ΔG. This free energy change depends upon the temperature & concentrations according to   ΔG = ΔG°  +  RTInQ  where ΔG° is the free energy change under conditions and Q is the thermodynamic reaction quotient. The free energy change is related to the cell potential  Ecell by ΔG= nFEcell

so for non-standard conditions
              -nFEcell = -nFE°cell  + RT InQ

or
   
              Ecell  =  E°cell - RT/nF (InQ) 

which is called Nernst equation.

Answer:

n and lnQ - doubled

Q - Squared

E, Edegree - No change

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