C4H8(g)⟶2C2H4(g) C4H8(g)⟶2C2H4(g) has an activation energy of 262 kJ/mol.262 kJ/mol. At 600.0 K,600.0 K, the rate constant, ????,k, is 6.1×10−8 s−1.6.1×10−8 s−1. What is the value of the rate constant at 725.0 K?

Respuesta :

Answer:

Rate constant at 725 K is [tex]5.2\times 10^{-4}s^{-1}[/tex]

Explanation:

According to Arrhenius equation for a reaction-

[tex]ln(\frac{k_{2}}{k_{1}})=\frac{E_{a}}{R}(\frac{1}{T_{1}}-\frac{1}{T_{2}})[/tex]

where [tex]k_{2}[/tex] and [tex]k_{1}[/tex] are rate constants of reaction at [tex]T_{2}[/tex] and [tex]T_{1}[/tex] temperatures (in kelvin) respectively.

[tex]E_{a}[/tex] is activation energy of reaction.

Here [tex]T_{1}[/tex]= 600 K , [tex]k_{1}[/tex]= [tex]6.1\times 10^{-8}s^{-1}[/tex]

[tex]T_{2}[/tex]= 725 K, [tex]E_{a}[/tex]= 262 kJ/mol and R = 8.314 J/(mol.K)

So plugin all the values in the above equation-

[tex]ln(\frac{k_{2}}{6.1\times 10^{-8}s^{-1}})=\frac{262\times 10^{3}J/mol}{8.314J/(mol.K)}\times (\frac{1}{600K}-\frac{1}{725K})[/tex]

So, [tex]k_{2}[/tex] = [tex]5.2\times 10^{-4}s^{-1}[/tex]

Hence rate constant at 725 K is [tex]5.2\times 10^{-4}s^{-1}[/tex]