Solution of the Schrödinger wave equation for the hydrogen atom results in a set of functions (orbitals) that describe the behavior of the electron. Each function is characterized by 3 quantum numbers: n, l, and ml. If the value of n = 1 ... The quantum number l can have values from to . ... The total number of orbitals possible at the n = 1 energy level is . If the value of l = 1 ... The quantum number ml can have values from to . ... The total number of orbitals possible at the l = 1 sublevel is .

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Answer:

If n=1, l can only have the value l=0 and the total number of orbitals is 0. If l=1, ml can be -1,0 or 1 and the total number of orbitals at l=1 is 3.

Explanation:

When solving the radial part of Schrödinger equation, one needs to expand in power series that lead to Laguerre polynomials of the form [tex]L_{n-l-1}(r)[/tex], being n and l the quantum numbers. As is known, in the Laguerre polynomials the subindex must be greater than or equal to 0, which implies [tex]n-l-1\geq0[/tex]. So if n=1, the only possible value of l is l=0.

Likewise, when solving the angular part, one gets the spherical harmonics [tex]Y_{l,m_l}(\theta,\phi)[\tex] as solution. One of the properties of spherical harmonics is that the number [tex]m_l[\tex] can only take the values  [tex]m_l=-l,-l+1,-l+2,...,l-1,l[\tex]. So if l=0, as above, [tex]m_l[\tex] can only take the value [tex]m_l=0,[\tex] thus giving only 1 orbital. But if l=1, [tex]m_l[/tex] can be [tex]m_l=-1,0,1[/tex]. Therefore the sublevel l=| has 3 possible orbitals.