A hot 123.3 g lump of an unknown substance initially at 164.2 °C is placed in 35.0 mL of water initially at 25.0 °C and the system is allowed to reach thermal equilibrium. The final temperature of the system is 48.6 °C. What is the identity of the unknown substance? Assume no heat is lost to the surroundings.

Respuesta :

Answer:

The unknown substance is rhodium.

Explanation:

Heat lost by hot substance will be equal to heat gained by the water

[tex]-Q_1=Q_2[/tex]

Mass of substance= [tex]m_1=123.3 g[/tex]

Specific heat capacity of substance= [tex]c_1=?[/tex]

Initial temperature of the substance = [tex]T_1=164.2^oC[/tex]

Final temperature of substance= [tex]T_2=T=48.6^oC[/tex]

[tex]Q_1=m_1c_1\times (T-T_1)[/tex]

Mass of water = M

Volume of water ,V= 35 ml

Density of water = d = 1.00 g/mL

[tex]M=d\times V=1.00 g/ml\times 35 mL=35 g[/tex]

Mass of water= [tex]M = m_2=35 g[/tex]

Specific heat capacity of water= [tex]c_2=4.184 J/g^oC [/tex]

Initial temperature of the water = [tex]T_3=25.0^oC[/tex]

Final temperature of water = [tex]T_3=T=48.6^oC[/tex]

[tex]Q_2=m_2c_2\times (T-T_3)[/tex]

[tex]-Q_1=Q_2[/tex]

[tex]-(m_1c_1\times (T-T_1))=m_2c_2\times (T-T_3)[/tex]

On substituting all values:

we get, [tex]c_1 =0.242 J/g^oC [/tex]

The value of heat capacity of the substance is equal to that of rhodium metal.Hence, the unknown substance is rhodium.