The isomerization of methylisonitrile to acetonitrile is first order in CH3NC. CH3NC(g) → CH3CN(g) The half life of the reaction is 1.60 × 105 s at 444 K. What is the rate constant when the initial [CH3NC] is 0.030 M?

Respuesta :

Answer: The rate constant for the given reaction is [tex]4.33\times 10^{-6}s^{-1}[/tex]

Explanation:

For the given chemical equation:

[tex]CH_3NC(g)\rightarrow CH_3CN(g)[/tex]

We are given that the above equation is undergoing first order kinetics.

The equation used to calculate rate constant from given half life for first order kinetics:

[tex]t_{1/2}=\frac{0.693}{k}[/tex]

The rate constant is independent of  the initial concentration for first order kinetics.

We are given:

[tex]t_{1/2}[/tex] = half life of the reaction = [tex]1.60\times 10^5s[/tex]

Putting values in above equation, we get:

[tex]k=\frac{0.693}{1.60\times 10^5s}=4.33\times 10^{-6}s^{-1}[/tex]

Hence, the rate constant for the given reaction is [tex]4.33\times 10^{-6}s^{-1}[/tex]

The rate constant when the initial [CH3NC] is 0.030 M will be equal to [tex]4.33*10^-^6s^-^1[/tex]

How can we arrive at this result?

  • We will use the equation to calculate the half-life constant.

The equation is: [tex]k= \frac{0.693}{T_\frac{1}{2} }[/tex]

In this case, the symbol [tex]T_\frac{1}{2}[/tex] refers to the half-life value that we have in the above question.

  • Now, we can substitute the values into the equation and solve it as follows:

[tex]k=\frac{0.693}{1.60*10^-^6s} = 4.33*10^-^6s^-^1[/tex]

More information about half-life in the link:

https://brainly.com/question/11152793