If it takes 87.0 min for the concentration of a reactant to drop to 20.0% of its initial value in a first-order reaction, what is the rate constant for the reaction in the units min-1?

Respuesta :

Answer:

0.0185 min⁻¹

Explanation:

Using integrated rate law for first order kinetics as:

[tex][A_t]=[A_0]e^{-kt}[/tex]

Where,  

[tex][A_t][/tex] is the concentration at time t

[tex][A_0][/tex] is the initial concentration

Given:

20.0 % of the initial values is left which means that 0.20 of [tex][A_0][/tex] is left. So,

[tex]\frac {[A_t]}{[A_0]}[/tex] = 0.20

t = 87.0 min

[tex]\frac {[A_t]}{[A_0]}=e^{-k\times t}[/tex]

[tex]0.20=e^{-k\times 87.0}[/tex]

k = 0.0185 min⁻¹