A weak acid with a Ka of 4.0 x 10-4 is mixed with its sodium salt to form a solution that contains twice as many moles of the sodium salt than of the weak acid. What is the pH of the solution?

Respuesta :

Answer:

pH of the solution is 3.70

Explanation:

The given weak acid (HA) and it's sodium salt (NaA) forms a buffer system. According to Henderson-Hasselbalch equation for this buffer system-

[tex]pH=pK_{a}+log(\frac{n_{A^{-}}}{n_{HA}})[/tex]

Where, [tex]n_{A^{-}}[/tex] and [tex]n_{HA}[/tex] represent number of moles of [tex]A^{-}[/tex] ion and HA respectively.

Here [tex]\frac{n_{A^{-}}}{n_{HA}}=2[/tex]  and [tex]pK_{a}=-logK_{a}=-log(4.0\times 10^{-4})=3.40[/tex]

So, [tex]pH=3.40+log2=3.70[/tex]

Hence pH of the solution is 3.70