Suppose 45.0 g of water at 85 °C is added to 105.0 g of ice at 0 °C. The molar heat of fusion of water is 6.01 kJ/mol, and the specific heat of water is 4.18 J/g °C. On the basis of these data, (a) what will be the final temperature of the mixture and (b) how many grams of ice will melt?

Respuesta :

Answer:

A. Final Temp = 36.428C and

47.9g ice will melt

Explanation:

Given the following data:

Mass of water (M1) = 45.0g = 0.045kg

Temperature (T1) = 85C = 358k

Mass of ice (M2) = 105g = 0.105kg

Temperature (T2) = 0c = 273k

Specific heat of water (C) = 4.18j/gC = 0.00418kj/kgc

Molar heat of fusion of water = 6.01kj/mol

Therefore, heat required (q) = MCT

M1C(T1-T2) = M2C∆T

By putting the data we have

0.045×0.00418×(358-273) = 0.105×0.00418×∆T

∆t = 0.045×0.00418×85/0.105×0.00418

∆t = 36.428C

Gram of ice that would melt would be 47.9g

Part(a): The final temperature of the mixture is  [tex]36.428^{\circ} C[/tex]

Part(b): The amount of ice that will melt is  57.13 g

Part(a):

Given,

Mass of water = 45.0 g

The initial temperature of water =

Mass of ice = 105.0 g

The temperature of ice =

Molar heat of fusion of water =[tex]6.01 kJ/mol = 0.334 kJ/g[/tex]

Specific heat of water =[tex]4.18 J/gC^{\circ}[/tex]

The formula for the required heat is,

[tex]m_1c(T_1-T_2)=m_2c\bigtriangleup T[/tex]

Now, substituting the given data into the above formula we get,

[tex]\bigtriangleup T= 0.045\times0.00418\times\frac{85}{0.105} \times0.00418\\\bigtriangleup T=36.428^{\circ} C[/tex]

Part(b):

The heat is taken by water to cool from [tex]85^{\circ}C[/tex] to [tex]0^{\circ}C[/tex] is,

[tex]ms\bigtriangleup T=45.0\times4.18\times(85-0)\\= 15988.5 J[/tex]

Heat given by ice to melt at [tex]0^{\circ}[/tex] is,

[tex]105\times0.334=35.07 kJ[/tex]

It may be seen that the amount of ice is in excess to cool water from [tex]85^{\circ}C[/tex] to [tex]0^{\circ}C[/tex] as it gives out more heat than that required by water to cool to [tex]0^{\circ}C[/tex]

Calculation of the amount of ice required to cool water from  [tex]85^{\circ}C[/tex] to [tex]0^{\circ}C[/tex] is,

[tex]15.9885 kJ = m \times 0.334 kJ/g\\m=47.87 g[/tex]

So, the ice will melt is,

[tex]105.0 g- 47.87 g= 57.13 g[/tex]

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