The thermal decomposition of N2O5 obeys first-order kinetics. At 45°C, a plot of ln[N2O5] versus t gives a slope of −6.40 × 10−4 min−1. What is the half-life of the reaction?

Respuesta :

Answer:

  • 1,080 min

Explanation:

A first order reaction follows the law:

     [tex]rate=k[A][/tex]  , where [A] is the concentraion of the reactant A.

Equivalently:

       [tex]\dfrac{d[A]}{dt}=-k[A][/tex]

Integrating:

    [tex]\dfrac{d[A]}{[A]}=-kdt[/tex]

   [tex]\ln \dfrac{[A]}{[A_o]}=-kt[/tex]

Half-life means [A]/[A₀] = 1/2, t = t½:

  •    t½ = ln (2) / k

That means that the half-life is constant.

The slope of the plot of ln [N₂O₅]  is -k. Then k is equal to 6.40 × 10⁻⁴ min⁻¹.

Thus, you can calculate t½:

   t½ = ln(2) / 6.40 × 10⁻⁴ min⁻¹

   t½ = 1,083 min.

Rounding to 3 significant figures, that is 1,080 min.

The half-life of the reaction is 1.080 min. As given the order of the reaction is first order.

Half-life for a first-order reaction:

The rate of the reaction for a first-order reaction can be given as:

Rate= k[A]

Half-life means:

[A]/[A₀] = 1/2, t = t½:

t½ = ln (2) / k

That means that the half-life is constant.

The slope of the plot of ln [N₂O₅]  is -k.

Then k is equal to 6.40 × 10⁻⁴ min⁻¹.

Calculation for t½:

t½ = ln(2) / 6.40 × 10⁻⁴ min⁻¹

t½ = 1.083 min

Thus, the half-life of this reaction is 1.083 min.

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