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No two electrons in an atom or molecule may have the same four electronic quantum numbers, according to the Pauli Exclusion Principle. Only two electrons can fit into an orbital at a time, hence they must have opposing spins.

What is Pauli's exclusion principle ?

According to Pauli's Exclusion Principle, no two electrons in the same atom can have values for all four of their quantum numbers that are exactly the same. In other words, two electrons in the same orbital must have opposing spins and no more than two electrons can occupy the same orbital.

  • The reason it is known as the exclusion principle is because it states that all other electrons in an atom are excluded if one electron in the atom has the same specific values for all four quantum numbers.

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