The odds of finding the energy concentrated on just a few molecules in a macroscopically-measurable sample are very less likely.
If energy was only concentrated onto one molecule, the law of entropy is not followed because the system becomes organized into that one molecule only and the other molecules do not have energy. Due to the property of entropy, the energy will more likely be spread among all molecules rather than just one molecule.
Free atoms have greater entropy than molecules. The entropy of a substance increases with its molecular weight and complexity and with temperature.
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