A 0.0500-kg ice cube at −30.0ºC is placed in 0.400 kg of 35.0ºC water in a very well-insulated container. What is the final temperature?

Respuesta :

The amount of heat that is gained by water is equal to the amount of heat loss by the ice. Therefore, we have the following relationship:

[tex]-Q_w=Q_i[/tex]

Where "Qw" is the heat of water and "Qi" is the heat of ice. The heat of water is given by:

[tex]Q_w=m_wC_w(T_f-T_{0w})[/tex]

The amount of heat of ice must be calculated for the two states, solid and liquid. For the solid-state the temperature will be from -30 degrees to 0 degrees, therefore, we have:

[tex]Q_i=m_iC_i(T_f-T_{0i})[/tex]

Where Ci is the specific heat of ice in solid-state and is equal to:

[tex]C_i=2090\frac{kJ}{\operatorname{kg}}[/tex]

Replacing the values:

[tex]Q_i=(0.05\operatorname{kg})(2090\frac{kJ}{\operatorname{kg}K})(0-(-30C))[/tex]

Solving the operations we get:

[tex]Q_i=3135J[/tex]

Now we need to determine the amount of heat that needs the ice to convert into liquid. This is given by:

[tex]Q_{i-l}=m_iL_f[/tex]

Lf is the latent heat of ice and is equal to:

[tex]L_f=334\frac{kJ}{\operatorname{kg}}[/tex]

Replacing the values we get:

[tex]Q_{i-l}=(0.05\operatorname{kg})(334\frac{kJ}{\operatorname{kg}})[/tex]

Solving the operations:

[tex]Q_{i-l}=16.7kJ=16700J[/tex]

Now we need the amount of heat of liquid ice to its final temperature, this is given by:

[tex]Q_l=m_iC_l(T_f-0)[/tex]

Applying the relationship:

[tex]-m_wC_w(T_f-T_{0w})=m_iC_i(T_f-T_{0i})+m_iL_f+m_iC_w(T_f-0)[/tex]

Cw is the specific heat of water and is equal to:

[tex]C_w=4184\frac{J}{\operatorname{kg}K}[/tex]

And the specific heat of ice is:

[tex]C_i=4184\frac{J}{\operatorname{kg}K}[/tex]

Replacing the values. The first two terms on the right side we already calculated and the final temperature is the same for both:

[tex]-(0.4\operatorname{kg})(4184\frac{kJ}{\operatorname{kg}K})(T_f-35)=3135J+16700J+(0.05)(4184\frac{kJ}{\operatorname{kg}K})(T_f)[/tex]

Solving operations:

[tex]-1673.6\frac{kJ}{K}(T_f-35)=19835J+209.2\frac{kJ}{K}T_f[/tex]

Now we solve for the final temperature:

[tex]-1673.6T_f+58576=19835+209.2T_f[/tex]

Subtracting 19835 to both sideS:

[tex]\begin{gathered} -1673.6T_f+58576-19835=209.2T_f \\ -1673.6T_f+38741=209.2T_f \end{gathered}[/tex]

Now we add 1673Tf to both sides:

[tex]\begin{gathered} 38741=209.2T_f+1673.6T_f \\ 38741=1882.8T_f \end{gathered}[/tex]

Now we divide both sides by 1882.2

[tex]\frac{38741}{1882.8}=T_f[/tex][tex]20.57=T_f[/tex]

Therefore, the final temperature is 20.57 °C. This value can be converted into Kelvin using the following relationship:

[tex]T_K=T_C+273.15[/tex]

Replacing the temperature:

[tex]T_K=20.57+273.15=293.72[/tex]

Therefore, the final temperature is 293.72 K.