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Two experimental runs are performed to determine the calorimetric properties of an alcohol that has a melting point of -10°C. In the first run, a 200-g cube of frozen alcohol, at the melting point, is added to 300 g of water at 20°C in a styrofoam container. When thermal equilibrium is reached, the alcohol-water solution is at a temperature of 5.0°C. In the second run, an identical cube of alcohol is added to 500 g of water at 20°C and the temperature at thermal equilibrium is 10°C. The specific heat of water is 4190 J/kg · K. Assume that no heat is exchanged with the styrofoam container and with the surroundings. The heat of fusion of the alcohol is closest to

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Answer:

To find the heat of fusion (\(Q_f\)) of the alcohol, we can use the principle of conservation of energy. The heat gained by the water equals the heat lost by the alcohol during the phase change and temperature change.

Let's denote:

- \(m_{\text{water}}\) as the mass of water

- \(m_{\text{alcohol}}\) as the mass of alcohol

- \(T_{\text{initial}}\) as the initial temperature

- \(T_{\text{final}}\) as the final temperature after reaching thermal equilibrium

- \(C_{\text{water}}\) as the specific heat of water

- \(Q_f\) as the heat of fusion of the alcohol

For the first run:

\[Q_{\text{water}} = m_{\text{water}} \cdot C_{\text{water}} \cdot (T_{\text{final}} - T_{\text{initial}})\]

\[Q_{\text{alcohol}} = -Q_f\]

For the second run:

\[Q_{\text{water}} = m_{\text{water}} \cdot C_{\text{water}} \cdot (T_{\text{final}} - T_{\text{initial}})\]

\[Q_{\text{alcohol}} = -Q_f\]

Since the two runs involve the same cube of alcohol, we can set \(Q_{\text{alcohol}}\) for both runs equal to each other.

Solving the equations with the given values, you can find the heat of fusion (\(Q_f\)).