Respuesta :

Q1)
formal charges for atoms are assigned, this charge can be calculated using the following formula;
f.c = number of valence electrons - non bonding electrons around the atom - number of bonds

3 structures have been given, lets calculate for each structure 
A. 
charges for the atoms 
 H = 1-0-1=0
C = 4 -4-2 = -2
N = 5 - 0-4 = 1
O = 6 - 2 - 3 = 1

B.
H = 1-0-1 = 0
C = 4 - 0 - 4 =0
N = 5 - 0 - 4 = 1
O = 6 - 6 - 1 = -1

C.
H = 1-0-1 = 0
C = 4 - 2 - 3 = -1
N = 5 - 0 - 4 = 1
O = 6 - 4 - 2 = 0

Q2)
next we need to see which structure is most favoured.
the structure with least number of atoms that have a charge.
structure B and C have 2 atoms with charges whereas A has three atoms with charges, including an atom with -2 charge which is not common. so structure A can be disregarded.
another rule is that the more electronegative atom should have the more negative charge than less electronegative atoms. In structure C, Carbon the less electronegative atom compared to N and O, has -1 value and its more negative than the charges on N and O.
structure B on the other hand, O the more electronegative atom has -1 charge and C has 0 charge. Therefore the more favoured structure is B.
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Answer:

The second structure is the most stable of all three.

Explanation:

The Formal Charge in the different resonance structures of HCNO is,

[tex]\rm FC=V-N+B[/tex]

Where,

FC- Formal charge

V- Valence Electron

N- Non-bonding Electron

B- Number of bonds

So,  Formal charge In the atoms of first resonance structure is

H = 1-0+1=0

C = 4 -4+2 = -2

N = 5 - 0+4 = 1

O = 6 - 2 + 3 = 1

Formal charge In the atoms of Second resonance structure is

H = 1-0+1 = 0

C = 4 - 0 + 4 =0

N = 5 - 0 + 4 = 1

O = 6 - 6+1 = -1

Formal charge In the atoms of Third resonance structure is

H = 1-0 + 1 = 0

C = 4 - 2 +3 = -1

N = 5 - 0 + 4 = 1

O = 6 - 4 +2 = 0  

To Figure out the most stable resonance structure we have to keep two things in mind:

1) The stable molecular structure tend to have the least number of charged atom.

2) In a stable molecular structure the negative charge is present in the more electronegative atom.

Here decreasing order of electronegativity is,

 N > O > C > H

From the Explanation above, the second structure (B) follows both points

Therefore, The second structure is the most stable of all three.

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